Comparison Equation Approach to the Locking of Electronic Angular Momentum to the Molecular Axis in Atomic Collisions

نویسنده

  • Evgueni E. Nikitin
چکیده

A comparison equation is set up and solved for the locking of an electronic angular momentum 1 = 1 to the molecular axis during a collision of two atoms. Two parameters which enter into the comparison equation characterize the strength and the abruptness of the locking. A solution found allows one to investigate the transition from loose locking to tight locking. A new definition of the locking distance is suggested. A method to calculate the slipping probability which describes the deviation of the locking event from its sudden limit is proposed.

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تاریخ انتشار 2003